In gallium the funnel disappears on the proto level, setting free
its two contained segments, each of which forms a cylinder, thus yielding
twelve bodies on the proto level. On the meta, the three upper globes in
each left-hand segment are set free, and soon vanish, each liberating a
cigar and two septets, the quartet and triad uniting. On the hyper the
quartet yields two duads but the triangle persists. The second set of bodies
divide on the meta level, forming a sextet and a cross with a duad at each
arm; these on the hyper level divide into two triangles, four duads and a
unit. The seven-atomed cone becomes two triangles united by a single atom,
and on the meta level these form a ring round the unit; on the hyper they
form three duads and a unit.
In the right-hand segment, the same
policy is followed, the four triads becoming two sextets, while the central
body adds a third to the number. The second ring has a quartet instead of the
sextet, but otherwise breaks up as does that of the left; the quintet at the
base follows that of boron.
INDIUM (Plate XIII, 3).
The
complication of three segments of different types in each funnel does not
affect the process of breaking up, and indium needs little attention. A is
exactly the same as the left-hand funnel of gallium, save for
the substitution of a globe containing the familiar "cigar" and
two square-based pyramids. B is the same as the right-hand funnel of
gallium, except that its lowest body consists of two square-based pyramids
and a tetrahedron. All these are familiar.
PHOSPHORUS (Plate XIV,
1).
[Illustration]
The atoms in the six similar spheres in the
segments of the phosphorus funnel are arranged on the eight angles of a cube,
and the central one is attached to all of them. On the meta level five of the
nine atoms hold together and place themselves on the angles of a square-based
pyramid; the remaining four set themselves on the angle of a tetrahedron.
They yield, on the hyper level, two triads, a duad, and a unit. The remaining
bodies are simple and familiar.
ARSENIC (Plate XIV, 2).
Arsenic
shows the same ovoids and globe as have already been broken up in aluminium
(see _ante_); the remaining sixteen spheres form nine-atomed bodies on the
meta level, all similar to those of aluminium, thus yielding twelve positive
and twelve negative; the globe also yields a nine-atomed body, twenty-five
bodies of nine.
ANTIMONY (Plate XIV, 3).
Antimony follows closely
in the track of gallium and indium, the upper ring of spheres being
identical. In the second ring, a triplet is substituted for the unit, and
this apparently throws the cross out of gear, and we have a new eleven-atomed
figure, which breaks up into a triplet and two quartets on the hyper level.
The lowest seven-atomed sphere of the three at the base is the same as we met
with in copper.
* * * *
*
VIII.
IV.--THE OCTAHEDRAL GROUPS.
These groups are at the
turns of the spiral in Sir William Crookes' lemniscates (see p. 28). On the
one side is carbon, with below it titanium and zirconium; on the other
silicon, with germanium and tin. The characteristic form is an octahedron,
rounded at the angles and a little depressed between the faces in consequence
of the rounding; in fact, we did not, at first, recognize it as an
octahedron, and we called it the "corded bale," the nearest likeness that
struck us. The members of the group are all tetrads, and have eight funnels,
opening on the eight faces of the octahedron. The first group is paramagnetic
and positive; the corresponding one is diamagnetic and negative. The two
groups are not closely allied in composition, though both titanium and tin
have in common the five intersecting tetrahedra at their respective
centres.
[Illustration: PLATE XV.]
CARBON (Plate III, 5, and XV,
1) gives us the fundamental octahedral form, which becomes so masked in
titanium and zirconium. As before said (p. 30), the protrusion of the arms in
these suggests the old Rosicrucian symbol of the cross and rose, but they
show at their ends the eight carbon funnels with their characteristic
contents, and thus justify their relationship. The funnels are in pairs, one
of each pair showing three "cigars," and having as its fellow a funnel in
which the middle "cigar" is truncated, thus loosing one atom. Each "cigar"
has a leaf-like body at its base, and in the centre of the octahedron is a
globe containing four atoms, each within its own wall; these lie on the
dividing lines of the faces, and each holds a pair of the funnels together.
It seems as though this atom had been economically taken from the "cigar" to
form a link. This will be more clearly seen when we come to separate the
parts from each other. It will be noticed that the atoms in the "leaves" at
the base vary in arrangement, being alternately in a line and in a
triangle.
{ left 27 CARBON: One pair of
funnels { right 22 { centre
1 -- 54 4
pairs of funnels of 54 atoms 216 Atomic
weight 11.91 Number weight 216/18
12.00 TITANIUM (Plate III, 6, and XV, 2) has a complete carbon atom
distributed over the ends of its four arms, a pair of funnels with their
linking atom being seen in each. Then, in each arm, comes the elaborate body
shown as 3 _c_, with its eighty-eight atoms. A ring of twelve ovoids (3 _d_)
each holding within itself fourteen atoms, distributed among three
contained globes--two quartets and a sextet--is a new device for crowding
in material. Lastly comes the central body (4 _e_) of five
intersecting tetrahedra, with a "cigar" at each of their twenty points--of
which only fifteen can be shown in the diagram--and a ring of seven atoms
round an eighth, that forms the minute centre of the whole. Into this
elaborate body one hundred and twenty-eight atoms are built.
TITANIUM:
One carbon atom 216 4 _c_ of 88
atoms 352 12 _d_ of 14 " 168 Central
globe 128
---- Total
864 ---- Atomic
weight 47.74 Number weight
864/18 48.00 ZIRCONIUM (Plate XV, 3) has exactly the same outline as
titanium, the carbon atom is similarly distributed, and the central body is
identical. Only in 5 _c_ and _d_ do we find a difference on comparing them
with 4 _c_ and d. The _c_ ovoid in zirconium shows no less than fifteen
secondary globes within the five contained in the ovoid, and these, in turn,
contain altogether sixty-nine smaller spheres, with two hundred and twelve
atoms within them, arranged in pairs, triplets, quartets, quintets, a sextet
and septets. Finally, the ovoids of the ring are also made more
elaborate, showing thirty-six atoms instead of fourteen. In this way the
clever builders have piled up in zirconium no less than 1624
atoms.
ZIRCONIUM: One Carbon atom 216 4 _c_ of
212 atoms 848 12 _d_ of 36 " 432
Central globe 128
---- Total 1624
---- Atomic weight 89.85 Number
weight 90.22 [Illustration: PLATE XVI.]
SILICON (Plate
XVI, 1) is at the head of the group which corresponds to carbon on the
opposite turn of the lemniscate. It has the usual eight funnels, containing
four ovoids in a circle, and a truncated "cigar" but no central body of any
kind. All the funnels are alike.
SILICON: 8 funnels of 65
atoms 520 Atomic weight 28.18
Number weight 520/18 28.88 GERMANIUM (Plate XVI, 2) shows the eight
funnels, containing each four segments (XVI, 4), within which are three
ovoids and a "cigar." In this case the funnels radiate from a central globe,
formed of two intersecting tetrahedra, with "cigars" at each point enclosing
a four-atomed globe.
GERMANIUM: 8 funnels of 156 atoms
1248 Central
globe 52 ----
Total 1300 ----
Atomic weight 71.93 Number weight 1300/18
72.22 TIN (Plate XVI, 3) repeats the funnel of germanium, and the central
globe we met with in titanium, of five intersecting tetrahedra, carrying
twenty "cigars"; the latter, however, omits the eight-atomed centre of the
globe that was found in titanium, and hence has one hundred and twenty
atoms therein instead of one hundred and twenty-eight. Tin, to make room for
the necessary increase of atoms, adopts the system of spikes, which we met
with in zinc (see Plate IX, 2); these spikes, like the funnels, radiate from
the central globe, but are only six in number. The twenty-one-atomed cone
at the head of the spike we have already seen in silver, and we shall
again find it in iridium and platinum; the pillars are new in detail though
not in principle, the contained globes yielding a series of a triplet,
quintet, sextet, septet, sextet, quintet, triplet.
TIN: 8 funnels of
156 atoms 1248 6 spikes of 126 " 756
Central globe
120 ---- Total
2124 ---- Atomic
weight 118.10 Number weight
2124/18 118.00 V.--THE BARS GROUPS.
[Illustration: PLATE
XVII.]
Here, for the first time, we find ourselves a little at issue with
the accepted system of chemistry. Fluorine stands at the head of
a group--called the inter-periodic--whereof the remaining members are
(see Crookes' table, p. 28), manganese, iron, cobalt, nickel;
ruthenium, rhodium, palladium; osmium, iridium, platinum. If we take all
these as group V, we find that fluorine and manganese are violently forced
into company with which they have hardly any points of relationship, and
that they intrude into an otherwise very harmonious group of closely
similar composition. Moreover, manganese reproduces the characteristic
lithium "spike" and not the bars of those into whose company it is thrust,
and it is thus allied with lithium, with which indeed it is almost identical.
But lithium is placed by Crookes at the head of a group, the other members
of which are potassium, rubidium and cæsium (the last not examined).
Following these identities of composition, I think it is better to remove
manganese and fluorine from their incongruous companions and place them with
lithium and its allies as V _a_, the Spike Groups, marking, by the identity
of number, similarities of arrangement which exist, and by the separation
the differences of composition. It is worth while noting what Sir
William Crookes, in his "Genesis of the Elements," remarks on the relations
of the interperiodic group with its neighbours. He says: "These bodies
are interperiodic because their atomic weights exclude them from the
small periods into which the other elements fall, and because their
chemical relations with some members of the neighbouring groups show that
they are probably interperiodic in the sense of being in transition
stages."
Group V in every case shows fourteen bars radiating from a
centre as shown in iron, Plate IV, 1. While the form remains unchanged
throughout, the increase of weight is gained by adding to the number of atoms
contained in a bar. The group is made up, not of single chemical elements, as
in all other cases, but of sub-groups, each containing three elements, and
the relations within each sub-group are very close; moreover the weights
only differ by two atoms per bar, making a weight difference of twenty-eight
in the whole. Thus we have per bar:--
Iron
72 Palladium 136 Nickel
74 Osmium 245 Cobalt 76 Iridium
247 Ruthenium 132 Platinum A 249 Rhodium
134 Platinum B 257 It will be noticed (Plate XVII, 3, 4, 5,) that
each bar has two sections, and that the three lower sections in iron, cobalt
and nickel are identical; in the upper sections, iron has a cone of
twenty-eight atoms, while cobalt and nickel have each three ovoids, and of
these the middle ones alone differ, and that only in their upper globes, this
globe being four-atomed in cobalt and six-atomed in nickel.
The long
ovoids within each bar revolve round the central axis of the bar, remaining
parallel with it, while each spins on its own axis; the iron cone spins round
as though impaled on the axis.
14 bars of 72
atoms 1008 Atomic weight
55.47 Number weight 1008/18 56.00 IRON (Plate IV, 1, and
XVII, 3):
14 bars of 74 atoms 1036 Atomic
weight 57.70 Number weight 1036/18
57.55 COBALT (Plate XVII, 4):
14 bars of 76 atoms
1064 Atomic weight 58.30 Number weight
1064/18 59.11 NICKEL (Plate XVII, 4):
(The weight of cobalt,
as given in Erdmann's _Lehrbuch_, is 58.55, but Messrs. Parker and Sexton, in
_Nature_, August 1, 1907, give the weight, as the result of their
experiments, as 57.7.)
[Illustration: PLATE XVIII.]
The next
sub-group, ruthenium, rhodium, and palladium, has nothing to detain us. It
will be observed that each bar contains eight segments, instead of the six of
cobalt and nickel; that ruthenium and palladium have the same number of atoms
in their upper ovoids, although in ruthenium a triplet and quartet represent
the septet of palladium; and that in ruthenium and rhodium the lower ovoids
are identical, though one has the order: sixteen, fourteen, sixteen,
fourteen; and the other: fourteen, sixteen, fourteen, sixteen. One constantly
asks oneself: What is the significance of these minute changes? Further
investigators will probably discover the answer.
14 bars of 132
atoms 1848 Atomic weight
100.91 Number weight 1848/18 102.66 RUTHENIUM (Plate
XVIII, 1):
14 bars of 134 atoms 1876 Atomic
weight 102.23 Number weight 1876/18
104.22 RHODIUM (Plate XVII, 2):
14 bars of 136
atoms 1904 Atomic weight
105.74 Number weight 1904/18 105.77 PALLADIUM (XVIII,
3):
The third sub-group, osmium, iridium and platinum, is, of course,
more complicated in its composition, but its builders succeed in preserving
the bar form, gaining the necessary increase by a multiplication of
contained spheres within the ovoids. Osmium has one peculiarity: the ovoid
marked _a_ (XVIII, 4) takes the place of axis in the upper half of the bar,
and the three ovoids, marked _b_, revolve round it. In the lower half, the
four ovoids, _c_, revolve round the central axis. In platinum, we have
marked two forms as platinum A and platinum B, the latter having two
four-atomed spheres (XVIII, 6 _b_) in the place of the two triplets marked a.
It may well be that what we have called platinum B is not a variety of
platinum, but a new element, the addition of two atoms in a bar being exactly
that which separates the other elements within each of the sub-groups. It
will be noticed that the four lower sections of the bars are identical in
all the members of this sub-group, each ovoid containing thirty atoms.
The upper ring of ovoids in iridium and platinum A are also identical, but
for the substitution, in platinum A, of a quartet for a triplet in the
second and third ovoids; their cones are identical, containing twenty-one
atoms, like those of silver and tin.
14 bars of 245
atoms 3430 Atomic weight 189.55
Number weight 3430/18 190.55 OSMIUM (Plate XVIII, 4):
14 bars of 247 atoms 3458 Atomic weight
191.11 Number weight 3458/18 192.11 IRIDIUM (Plate XVIII,
5):
14 bars of 249 atoms 3486 Atomic
weight 193.66 Number weight 3486/18
193.34 PLATINUM A (Plate XVIII, 6 _a_):
14 bars of 251
atoms 3514 Atomic weight ------
Number weight 3514/18 195.22 PLATINUM B (Plate XVIII, 6
_b_):
V a.--THE SPIKE GROUPS.
I place within this group lithium,
potassium, rubidium, fluorine, and manganese, because of their similarity in
internal composition. Manganese has fourteen spikes, arranged as in the iron
group, but radiating from a central globe. Potassium has nine, rubidium has
sixteen, in both cases radiating from a central globe. Lithium (Plate IV, 2)
and fluorine (Plate IV, 3) are the two types which dominate the group,
lithium supplying the spike which is reproduced in all of them, and fluorine
the "nitrogen balloon" which appears in all save lithium. It will be seen
that the natural affinities are strongly marked. They are all monads
and paramagnetic; lithium, potassium and rubidium are positive, while
fluorine and manganese are negative. We seem thus to have a pair,
corresponding with each other, as in other cases, and the interperiodic group
is left interperiodic and congruous within itself.
[Illustration:
PLATE XIX.]
LITHIUM (Plate IV, 2 and Plate XIX, 1) is a striking and
beautiful form, with its upright cone, or spike, its eight radiating petals
(_x_) at the base of the cone, and the plate-like support in the centre of
which is a globe, on which the spike rests. The spike revolves swiftly on its
axis, carrying the petals with it; the plate revolves equally swiftly in
the opposite direction. Within the spike are two globes and a long ovoid;
the spheres within the globe revolve as a cross; within the ovoid are
four spheres containing atoms arranged on tetrahedra, and a central sphere
with an axis of three atoms surrounded by a spinning wheel of
six.
LITHIUM: Spike of 63 atoms 63 8 petals
of 6 atoms 48 Central globe of 16 atoms
16
----
Total 127 ----
Atomic weight 6.98 Number weight
127/18 7.05 POTASSIUM (Plate XIX, 2) consists of nine radiating
lithium spikes, but has not petals; its central globe contains one hundred
and thirty-four atoms, consisting of the "nitrogen balloon," encircled by six
four-atomed spheres.
POTASSIUM: 9 bars of 63 atoms
567 Central
globe 134
---- Total
701 ---- Atomic
weight 38.94 Number weight 701/18
38.85 (The weight, as determined by Richards [_Nature_, July 18, 1907]
is 39.114.)
RUBIDIUM: (Plate XIX, 3) adds an ovoid, containing three
spheres--two triplets and a sextet--to the lithium spike, of which it has
sixteen, and its central globe is composed of three
"balloons."
RUBIDIUM: 16 spikes of 75
atoms 1200 Central globe
330
---- Total 1530
---- Atomic weight 84.85 Number weight
1530/18 85.00 The corresponding negative group consists only of
fluorine and manganese, so far as our investigations have
gone.
FLUORINE (Plate IV, 3, and Plate XVII, 1) is a most peculiar
looking object like a projectile, and gives one the impression of being ready
to shoot off on the smallest provocation. The eight spikes, reversed funnels,
coming to a point, are probably responsible for this warlike appearance.
The remainder of the body is occupied by two "balloons."
FLUORINE: 8
spikes of 15 atoms 120 2
balloons 220
----
Total 340
---- Atomic weight 18.90 Number weight
340/18 18.88 MANGANESE (Plate XVII, 2) has fourteen spikes radiating
from a central "balloon."
MANGANESE: 14 spikes of 63
atoms 882 Central
balloon 110
----
Total 992
---- Atomic weight 54.57 Number
weight 992/18 55.11 * * * *
*
IX.
We have now to consider the breaking up of the octahedral
groups, and more and more, as we proceed, do we find that the most
complicated arrangements are reducible to simple elements which are already
familiar.
CARBON (Plate III, 5, and XV,
1).
[Illustration]
Carbon is the typical octahedron, and a clear
understanding of this will enable us to follow easily the constitution and
disintegration of the various members of these groups. Its appearance as a
chemical atom is shown on Plate III, and see XV, 1. On the proto level the
chemical atom breaks up into four segments, each consisting of a pair of
funnels connected by a single atom; this is the proto element which appears
at the end of each arm of the cross in titanium and zirconium. On the meta
level the five six-atomed "cigars" show two neutral combinations, and the
truncated "cigar" of five atoms is also neutral; the "leaves" yield two forms
of triplet, five different types being thus yielded by each pair of
funnels, exclusive of the linking atom. The hyper level has triplets, duads
and units.
TITANIUM (Plate III, 6, and XV, 2,
3).
[Illustration]
On the proto level, the cross breaks up
completely, setting free the pairs of funnels with the linking atom (_a_ and
_b_), as in carbon, the four bodies marked _c_, the twelve marked _d_, and
the central globe marked e. The latter breaks up again, setting free its five
intersecting cigar-bearing tetrahedra, which follow their usual course (see
Occultum, p. 44). The eight-atomed body in the centre makes a ring of seven
atoms round a central one, like that in occultum (see p. 44, diagram B), from
which it only differs in having the central atom, and breaks up similarly,
setting the central atom free. The ovoid _c_ sets free its four contained
globes, and the ovoid _d_ sets free the three within it. Thus sixty-one
proto elements are yielded by titanium. On the meta level, _c_ (titanium
3) breaks up into star-like and cruciform bodies; the component parts of
these are easily followed; on the hyper level, of the four forms of triplets
one behaves as in carbon, and the others are shown, _a_, _b_ and _f_;
the cruciform quintet yields a triplet and a duad, _c_ and _d_; the
tetrahedra yield two triplets _g_ and _h_, and two units; the septet, a
triplet _k_ and a quartet _j_. On the meta level, the bodies from _d_ behave
like their equivalents in sodium, each _d_ shows two quartets and a sextet,
breaking up, on the hyper level, into four duads and two
triads.
ZIRCONIUM (Plate XV, 2, 5).
Zirconium reproduces in its
_c_ the four forms that we have already followed in the corresponding _c_ of
titanium, and as these are set free on the proto level, and follow the same
course on the meta and hyper levels, we need not repeat them. The central
globe of zirconium _c_ sets free its nine contained bodies; eight of these
are similar and are figured in the diagram; it will be observed that the
central body is the truncated "cigar" of carbon; their behaviour on the meta
and hyper levels is easily followed there. The central sphere is also
figured; the cigar follows its usual course, and its companions unite into a
sextet and an octet. The _d_ ovoid liberates five bodies, four of which we
have already seen in titanium, as the crosses and sextet of sodium, and which
are figured under titanium; the four quartets within the larger globe also
follow a sodium model, and are given again.
SILICON (Plate XVI,
1).
[Illustration]
In silicon, the ovoids are set free from the
funnels on the proto level, and the truncated "cigar," playing the part of a
leaf, is also liberated. This, and the four "cigars," which escape from their
ovoids, pass along their usual course. The quintet and quartet remain
together, and form a nine-atomed body on the meta level, yielding a sextet
and a triplet on the hyper.
GERMANIUM (Plate XVI, 2, 4).
The
central globe, with its two "cigar"-bearing tetrahedra, need not delay us;
the tetrahedra are set free and follow the occultum disintegration, and the
central four atoms is the sodium cross that we had in titanium. The ovoids
(XVI, 4) are liberated on the proto level, and the "cigar," as usual, bursts
its way through and goes along its accustomed path. The others remain linked
on the meta level, and break up into two triangles and a quintet on the
hyper.
TIN (Plate XVI, 3, 4).
Here we have only the spike to
consider, as the funnels are the same as in germanium, and the central globe
is that of titanium, omitting the eight atomed centre. The cone of the spike
we have had in silver (see p. 729, May), and it is set free on the proto
level. The spike, as in zinc, becomes a large sphere, with the single septet
in the centre, the remaining six bodies circling round it on differing
planes. They break up as shown. (Tin is Sn.)
IRON (Plate IV, I, and
XVII, 3).
[Illustration]
We have already dealt with the affinities
of this peculiar group, and we shall see, in the disintegration, even more
clearly, the close relationships which exist according to the classification
which we here follow.
The fourteen bars of iron break asunder on the
proto level, and each sets free its contents--a cone and three ovoids, which
as usual, become spheres. The twenty-eight-atomed cone becomes a four-sided
figure, and the ovoids show crystalline contents. They break up, on the meta
level as shown in the diagram, and are all reduced to triplets and duads on
the hyper level.
COBALT (Plate XVII, 4).
The ovoids in cobalt are
identical with those of iron; the higher ovoids, which replace the cone of
iron, show persistently the crystalline forms so noticeable throughout this
group.
NICKEL (Plate XVII, 5).
The two additional atoms in a bar,
which alone separate nickel from cobalt, are seen in the upper sphere of the
central ovoid.
RUTHENIUM (Plate XVIII, 1).
The lower ovoids in
ruthenium are identical in composition, with those of iron, cobalt and nickel
and may be studied under Iron. The upper ones only differ by the addition of
a triplet.
RHODIUM (Plate XVIII, 2).
Rhodium has a septet, which
is to be seen in the _c_ of titanium (see _k_ in the titanium diagram) and
differs only in this from its group.
PALLADIUM (Plate XVIII,
3).
In palladium this septet appears as the upper sphere in every ovoid
of the upper ring.
OSMIUM (Plate XVIII, 4).
We have here no new
constituents; the ovoids are set free on the proto level and the contained
globes on the meta, all being of familiar forms. The cigars, as usual, break
free on the proto level, and leave their ovoid with only four contained
spheres, which unite into two nine-atomed bodies as in silicon (see
above).
IRIDIUM (Plate XVIII, 5.)
The twenty-one-atomed cone of
silver here reappears, and its proceedings may be followed under that metal
(see diagram, p. 729, May). The remaining bodies call for no
remark.
PLATINUM (Plate XVIII, 6).
Again the silver cone is with
us. The remaining bodies are set free on the proto level, and their contained
spheres on the meta.
LITHIUM (Plate IV, 2, and XIX,
1).
[Illustration]
Here we have some new combinations, which recur
persistently in its allies. The bodies _a_, in Plate XIX, 1, are at the top
and bottom of the ellipse; they come to right and left of it in the proto
state, and each makes a twelve-atomed body on the meta level.
The five
bodies within the ellipse, three monads and two sextets, show two which we
have had before: _d_, which behaves like the quintet and quartet in silicon,
after their junction, and _b_, which we have had in iron. The two bodies _c_
are a variant of the square-based pyramid, one atom at the apex, and two at
each of the other angles. The globe, _e_, is a new form, the four tetrahedra
of the proto level making a single twelve-atomed one on the meta. The body
_a_ splits up into triplets on the hyper; _b_ and _d_ follow their iron and
silicon models; _c_ yields four duads and a unit; _e_ breaks into four
quartets.
POTASSIUM (Plate XIX, 2).
Potassium repeats the lithium
spike; the central globe shows the "nitrogen balloon," which we already know,
and which is surrounded on the proto level with six tetrahedra, which are set
free on the meta and behave as in cobalt. Hence we have nothing
new.
RUBIDIUM (Plate XIX, 3).
Again the lithium spike, modified
slightly by the introduction of an ovoid, in place of the top sphere; the
forms here are somewhat unusual, and the triangles of the sextet revolve
round each other on the meta level; all the triads break up on the hyper
level into duads and units.
FLUORINE (Plate IV, 3, and Plate XVII,
1).
The reversed funnels of fluorine split asunder on the proto level,
and are set free, the "balloons" also floating off independently. The
funnels, as usual, become spheres, and on the meta level set free their
contained bodies, three quartets and a triplet from each of the eight. The
balloons disintegrate in the usual way.
MANGANESE (Plate XVII,
2).
Manganese offers us nothing new, being composed of "lithium spikes"
and "nitrogen balloons."
* * * *
*
X.
VI.--THE STAR GROUPS.
We have now reached the last of
the groups as arranged on Sir William Crookes' lemniscates, that forming the
"neutral" column; it is headed by helium, which is _sui generis_. The
remainder are in the form of a flat star (see Plate IV, 4), with a centre
formed of five intersecting and "cigar"-bearing tetrahedra, and six radiating
arms. Ten of these have been observed, five pairs in which the second member
differs but slightly from the first; they are: Neon, Meta-neon; Argon,
Metargon; Krypton, Meta-krypton; Xenon, Meta-xenon; Kalon, Meta-kalon; the
last pair and the meta forms are not yet discovered by chemists. These all
show the presence of a periodic law; taking an arm of the star in each of the
five pairs, we find the number of atoms to be as follows :--
40
99 224 363 489 47 106 231 370 496 It
will be observed that the meta form in each case shows seven more atoms than
its fellow.
[Illustration: PLATE XX.]
HELIUM (Plate III, 5, and
Plate XX, 1) shows two "cigar"-bearing tetrahedra, and two hydrogen
triangles, the tetrahedra revolving round an egg-shaped central body, and the
triangles spinning on their own axes while performing a similar revolution.
The whole has an attractively airy appearance, as of a fairy
element.
HELIUM: Two tetrahedra of 24 atoms 48 Two triangles
of 9 atoms 18 Central egg
6 ----
Total 72
---- Atomic weight 3.94 Number weight
72/18 4.00 NEON (Plate XX, 2 and 6) has six arms of the pattern shown
in 2, radiating from the central globe.
NEON: Six arms of 40
atoms 240 Central tetrahedra
120
----
Total 360 ---- Atomic
weight 19.90 Number weight 360/18 20.00 META-NEON
(Plate XX, 3 and 6) differs from its comrade by the insertion of an
additional atom in each of the groups included in the second body within its
arm, and substituting a seven-atomed group for one of the triplets
in neon.
META-NEON: Six arms of 47 atoms 282 Central
tetrahedra 120 ---- Total 402 ---- Atomic
weight ---- Number weight 402/18
22.33 ARGON (Plate XX, 4, 6 and 7) shows within its arms the _b_ 63 which we
met in nitrogen, yttrium, vanadium and niobium, but not the "balloon," which
we shall find with it in krypton and its congeners.
ARGON: Six arms of
99 atoms 594 Central tetrahedra
120 ----
Total 714 ---- Atomic
weight 39.60 Number weight 714/18 39.66 METARGON (Plate
XX, 5, 6 and 7) again shows only an additional seven atoms in each
arm.
METARGON: Six arms of 106 atoms 636 Central
tetrahedra 120
---- Total
756 ---- Atomic
weight ---- Number weight 756/18
42 [Illustration: PLATE XXI.]
KRYPTON (Plate XXI, 1 and 4, and Plate
XX, 6 and 7) contains the nitrogen "balloon," elongated by its juxtaposition
to _b_ 63. The central tetrahedra appear as usual.
KRYPTON: Six arms
of 224 atoms 1344 Central tetrahedra
120
-----
Total 1464
----- Atomic weight 81.20 Number
weight 1464/18 81.33 META-KRYPTON differs only from krypton by the
substitution of _z_ for _y_ in each arm of the
star.
META-KRYPTON: Six arms of 231 atoms 1386
Central tetrahedra 120
-----
Total 1506
----- Atomic weight -----
Number weight 1506/18 83.66 XENON (Plate XXI, 2 and 4, and Plate XX, 6
and 7) has a peculiarity shared only by kalon, that _x_ and _y_ are
asymmetrical, the centre of one having three atoms and the centre of the
other two. Is this done in order to preserve the difference of seven from its
comrade?
XENON: Six arms of 363 atoms
2178 Central tetrahedra
120
-----
Total 2298
----- Atomic weight 127.10 Number
weight 2298/18 127.66 META-XENON differs from xenon only by the
substitution of two _z_'s for _x_ and _y_.
META-XENON: Six arms of
370 atoms 2220 Central tetrahedra
120
-----
Total 2340
----- Atomic weight ----- Number
weight 2340/18 130 KALON (Plate XXI, 3 and 4, and Plate XX, 6 and
7) has a curious cone, possessing a kind of tail which we have not observed
elsewhere; _x_ and _y_ show the same asymmetry as in xenon.
KALON: Six
arms of 489 atoms 2934 Central
tetrahedra 120 ---- Total
3054 ---- Atomic
weight ---- Number weight
3054/18 169.66 META-KALON again substitutes two _z_'s for _x_ and
_y_.
META-KALON: Six arms of 496 atoms
2976 Central tetrahedra
120 ---- Total
3096 ---- Atomic
weight ---- Number weight
3096/18 172 Only a few atoms of kalon and meta-kalon have been
found in the air of a fair-sized room.
It does not seem worth while to
break up these elements, for their component parts are so familiar. The
complicated groups--_a_ 110, _b_ 63 and _c_ 120--have all been fully dealt
with in preceding pages.
* * * *
*
There remains now only radium, of the elements which we have, so
far, examined, and that will be now described and will bring to an end
this series of observations. A piece of close and detailed work of this
kind, although necessarily imperfect, will have its value in the future,
when science along its own lines shall have confirmed these
researches.
It will have been observed that our weights, obtained by
counting, are almost invariably slightly in excess of the orthodox ones: it
is interesting that in the latest report of the International
Commission (November 13, 1907), printed in the _Proceedings of the Chemical
Society of London_, Vol. XXIV, No. 33, and issued on January 25, 1908, the
weight of hydrogen is now taken at 1.008 instead of at 1. This would slightly
raise all the orthodox weights; thus aluminium rises from 26.91 to 27.1,
antimony from 119.34 to 120.2, and so on.
* *
* * *
XI.
RADIUM.
[Illustration: PLATE
XXII.]
Radium has the form of a tetrahedron, and it is in the tetrahedral
groups (see article IV) that we shall find its nearest congeners;
calcium, strontium, chromium, molybdenum resemble it most closely in
general internal arrangements, with additions from zinc and cadmium. Radium
has a complex central sphere (Plate XXII), extraordinarily vivid and living;
the whirling motion is so rapid that continued accurate observation is
very difficult; the sphere is more closely compacted than the centre-piece
in other elements, and is much larger in proportion to the funnels and
spikes than is the case with the elements above named; reference to Plate
VIII will show that in these the funnels are much larger than the
centres, whereas in radium the diameter of the sphere and the length of the
funnel or spike are about equal. Its heart consists of a globe containing
seven atoms, which assume on the proto level the prismatic form shown in
cadmium, magnesium and selenium. This globe is the centre of two crosses, the
arms of which show respectively three-atomed and two-atomed groups. Round
this sphere are arranged, as on radii, twenty-four segments, each
containing five bodies--four quintets and a septet--and six loose atoms,
which float horizontally across the mouth of the segment; the whole sphere
has thus a kind of surface of atoms. On the proto level these six atoms in
each segment gather together and form a "cigar." In the rush of the
streams presently to be described one of these atoms is occasionally torn
away, but is generally, if not always, replaced by the capture of another which
is flung into the vacated space. |
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